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The U.S. Renewable Fuel Standard (RFS2) requires an increase in the use of advanced biofuels up to 36 billion gallons by 2022. Longer chain alcohols, in addition to cellulosic ethanol and synthetic biofuels, could be used to meet this demand while adhering to the RFS2 corn-based ethanol limitation. Higher carbon number alcohols can be utilized to improve the energy content, knock resistance, and/or petroleum displacement of gasoline-alcohol blends compared to traditional ethanol blends such as E10 while maintaining desired and regulated fuel properties. Part I of this paper focuses on the development of scenarios by which to compare higher alcohol fuel blends to traditional ethanol blends. It also details the implementation of fuel property prediction methods adapted from literature. Possible combinations of eight alcohols mixed with a gasoline blendstock were calculated and the properties of the theoretical fuel blends were predicted.

Striving for sustainable transportation solutions, hydrogen is often identified as a promising energy carrier and internal combustion engines are seen as a cost effective consumer of hydrogen to facilitate the development of a large-scale hydrogen infrastructure. Driven by efficiency and emissions targets defined by the U.S. Department of Energy, a research team at Argonne National Laboratory has worked on optimizing a spark-ignited direct injection engine for hydrogen. Using direct injection improves volumetric efficiency and provides the opportunity to properly stratify the fuel-air mixture in-cylinder. Collaborative 3D-CFD and experimental efforts have focused on optimizing the mixture stratification and have demonstrated the potential for high engine efficiency with low NOx emissions. Performance of the hydrogen engine is evaluated in this paper over a speed range from 1000 to 3000 RPM and a load range from 1.7 to 14.3 bar BMEP.

Energy security and climate change are two of the main drivers for development of sustainable and renewable transportation solutions. Entities around the globe have been working on strategic plans to reduce energy consumption and curb greenhouse gas emissions. In this context hydrogen is frequently mentioned as the fuel and energy carrier of the future. The U.S. Department of Energy's (DOE's) FreedomCAR and Vehicle Technologies (FCVT) Program has identified hydrogen-powered internal combustion engine (ICE) vehicles as an important mid-term technology on the path to a large-scale hydrogen economy. DOE has set challenging goals for hydrogen internal combustion engines including 45% peak brake thermal efficiency (BTE). This paper summarizes recent research engine test results employing hydrogen direct injection with different injection strategies.

This paper reviews and summarizes recent developments in hydrogen (H2) powered engine and vehicle research. Following an overview of mixture formation strategies, general trade-offs when operating engines on hydrogen are analyzed and highlights regarding accomplishments in efficiency improvement and emissions reduction are presented. These include estimates of efficiency potential of direct-injection hydrogen engines based on single-cylinder research engine data, fuel economy and emissions results of hydrogen powered passenger cars and pickup trucks as well as the impact and potential of hydrogen/methane blended operation.

This paper reports on research activities aiming to improve the efficiency of direct injected, hydrogen powered internal combustion engines. In a recent major change in the experimental setup the hydrogen single cylinder research engine at Argonne National Laboratory was upgraded to a new engine geometry providing increased compression ratio and a longer piston stroke compared to its predecessor. The higher compression ratio and the more advantageous volume to surface ratio of the combustion chamber are both intended to improve the overall efficiency of the experimental setup. Additionally, a new series of faster acting, piezo-activated injectors is used with the new engine providing increased flexibility for the optimization of DI injection strategies. This study focuses on the comparison of experimental data of the baseline versus the improved single cylinder research engine for similar engine operating conditions.

Alternative fuels for internal combustion engines have been the subject of numerous studies. The new U.S. Renewable Fuel Standard has made it a requirement to increase the production of ethanol and advanced biofuels to 36 billion gallons by 2022. Because corn-based ethanol will be capped at 15 billion gallons, 21 billion gallons must come from the advanced biofuels category. A potential source to fill the gap may be butanol and its isomers as they possess fuel properties superior to ethanol. Recently, concerns have been raised about emission of currently non-regulated constituents, aldehydes in particular, from alcohol-based fuels. In an effort to assess the relative impact of the U.S. Renewable Fuel Standards on emissions from a modern gasoline engine, both regulated and non-regulated gas constituents were measured from the combustion of three different alcohol isomers in a modern direct-injected (DI) spark ignition (SI) gasoline engine.

The application of hydrogen (H2) as an internal combustion (IC) engine fuel has been under investigation for several decades. The favorable physical properties of hydrogen make it an excellent alternative fuel for fuel cells as well as IC engines and hence it is widely regarded as the energy carrier of the future. The potential of hydrogen as an IC engine fuel can be optimized by direct injection (DI) as it provides multiple degrees of freedom to influence the in-cylinder combustion processes and consequently the engine efficiency and exhaust emissions. This paper studies a single-hole nozzle and examines the effects of injection strategy on engine efficiency, combustion behavior and NOx emissions. The experiments for this study are done on a 0.5 liter single-cylinder research engine which is specifically designed for combustion studies and equipped with a cylinder head that allows side as well as central injector location.

The potential exists to displace a portion of the petroleum diesel demand with butanol and positively impact engine-out particulate matter. As a preliminary investigation, 20% and 40% by volume blends of butanol with ultra low sulfur diesel fuel were operated in a 1999 Mercedes Benz C220 turbo diesel vehicle (Euro III compliant). Cold and hot start urban as well as highway drive cycle tests were performed for the two blends of butanol and compared to diesel fuel. In addition, 35 MPH and 55 MPH steady-state tests were conducted under varying road loads for the two fuel blends. Exhaust gas emissions, fuel consumption, and intake and exhaust temperatures were acquired for each test condition. Filter smoke numbers were also acquired during the steady-state tests. The results showed that for the urban drive cycle, both total hydrocarbon (THC) and carbon monoxide (CO) emissions increased as larger quantities of butanol were added to the diesel fuel.

The application of hydrogen (H2) as an internal combustion (IC) engine fuel has been under investigation for several decades. The favorable physical properties of hydrogen make it an excellent alternative fuel for IC engines and hence it is widely regarded as the energy carrier of the future. Direct injection of hydrogen allows optimizing this potential as it provides multiple degrees of freedom to influence the in-cylinder combustion processes and consequently engine efficiency and exhaust emissions. At certain operating conditions the stratification associated with hydrogen direct injection (DI) leads to an efficiency improvement. However, it also results in higher emissions levels. This paper examines the effects of combining an advanced direct injection strategy with water injection for efficiency benefits and emissions reduction of a hydrogen fuelled DI spark ignition (SI) engine.

Early in 2007 President Bush announced in his State of the Union Address a plan to off-set 20% of gasoline with alternative fuels in the next ten years. Ethanol, due to its excellent fuel properties for example, high octane number, renewable character, etc., appears to be a favorable alternative fuel from an engine perspective. Replacing gasoline with ethanol without any additional measures results in unacceptable disadvantages mainly in terms of vehicle range. This paper summarizes combustion studies performed with gasoline as well as blends of gasoline and ethanol. These tests were performed on a modern, 4-cylinder spark ignition engine with direct fuel injection and exhaust gas recirculation. To evaluate the influence of blending on the combustion behavior the engine was operated on the base gasoline calibration. Cylinder pressure data taken during the testing allowed for detailed analysis of rates of heat release and combustion stability.

In order to achieve the targets for hydrogen engines set by the U.S. Department of Energy (DOE) - a brake thermal efficiency of 45% and nitrogen oxide (NOx) emissions below 0.07 g/mi - while maintaining the same power density as comparable gasoline engines, researchers need to investigate advanced mixture formation and combustion strategies for hydrogen internal combustion engines. Hydrogen direct injection is a very promising approach to meeting DOE targets; however, there are several challenges to be overcome in order to establish this technology as a viable pathway toward a sustainable hydrogen infrastructure. This paper describes the use of endoscopic imaging as a diagnostic tool that allows further insight into the processes that occur during hydrogen combustion. It also addresses recent progress in the development of advanced direct-injected hydrogen internal combustion engine concepts.

This paper presents the results of efficiency, emissions, and performance testing of a supercharged, hydrogen-powered, four-cylinder engine. Tests were run at various speeds, loads, and air/fuel ratios in order to identify advantageous operating regimes. The tests revealed that a maximum thermal brake efficiency of 37% could be achieved and that certain operating regimes could achieve NOx emissions as low as 1 ppm without aftertreatment. Measurement of cylinder pressure traces in all four cylinders allowed a detailed assessment of cylinder-cylinder deviation. Several measures to further increase hydrogen engine performance in order to reach the goals set by the U.S. Department of Energy are being discussed.